!       Chalmers kinetics for NO/NO2 reactions on Pt/BaO/Al2O3
!
!        RATE = A T^n exp(-Ea/RT)
!
!        A : MOL/S or (M*M*M)/S per kg. of catalyst (washcoat)
!        Ea: J/MOL
!
!        SDEN : MOL/(M*M)
!
!        Cat. loading : SDEN * surface area of cat. per unit reactor volume
!                       {MOL/(M*M*M)}
!
!        Cat. loading :  1.0E+0 MOL/(M*M*M) 
!			 3.8E-3 MOL/(kg. of catalyst) 
!
!
!        Ref : A kinetic study of NO oxidation and NOx storage on Pt/Al2O3 
!              and Pt/BaO/Al2O3,J. Phys. Chem. B, 2001, 105
!
!        Contributor: Kalyan Chakravarthy, Oak Ridge National Laboratory
!                     e:mail: kalyan@msr.epm.ornl.gov
!                     phone : (865)574-3133
!	
ELEMENTS        N O
!
SPECIES		! MOL/(M*M*M)
        O2 NO NO2
END
!
SITE/PLATINUM   SDEN/2.7E-5/
        O(PT) NO(PT) NO2(PT) PT
END
REACTIONS
O2     + 2PT   <=> 2O(PT)                   6.6E2  0.0  30.4E3
                                        REV/3.8E12 0.0 209.4E3
				 COV/O(PT) 0.0 0.0 -23.0E3/	
NO     + PT    <=> NO(PT)                   2.5E4  0.0   0.0E0
                                        REV/3.8E13 0.0 115.5E3
NO2    + PT    <=> NO2(PT)                  2.4E4  0.0   0.0E0
                                        REV/3.8E13 0.0  97.9E3
		                 COV/O(PT) 0.0 0.0 -11.75E3/
NO(PT) + O(PT) <=> NO2(PT) + PT             3.8E10 0.0 101.3E3
                                        REV/2.2E10 0.0  52.5E3