The beneficial effect of SO2 on platinum migration and NO oxidation over diesel oxidation catalysts

Louise  Olsson, KCK, Chalmers

In this work we investigated NO oxidation over a model diesel oxidation catalyst (Pt/Al2O3). The NO oxidation activity was slowly decreasing during the whole 36 h of experiment and we propose that this is due to formation of platinum oxides, which we detected in an earlier study using XPS. However, the NO oxidation activity was completely regained after the introduction of a reducing agent, in this case propene at 400 C for 30 min. We also investigated the effect of long time exposure of SO2. The catalyst was exposed to 630 ppm NO+8% O2 for 30 min, which was followed by 22 h of 630 ppm NO+8% O2 + 30 ppm SO2. The NO oxidation activity decreased when introducing SO2. However, after about 3 h of SO2 the concentration of NO2 starts to increase from 30 ppm to 140 ppm after 22 h of SO2 exposure. The Pt dispersion before the long time SO2 exposure was 12%, but after this experiment only 3.5%. Thus, it is clear that SO2 exposure at this low temperature (250 C) causes a large Pt migration and sintering. Earlier studies have shown that it is beneficial with large Pt particles for NO oxidation. In addition, we conducted two temperature ramps with NO + O2, where one was done prior to the SO2 experiment and one after. We observed a dramatical increase in NO oxidation after the long SO2 exposure experiment. For example the NO2 production increased from 27% to 92% at 200 C.

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